杨海涛

   发布时间: 2014-07-16    访问次数: 1168

副教授 杨海涛

Email : yanght@cczu.edu.cn

教育经历:

  • 1996920007月: 安徽大学化学系应用化学专业;

  • 2000720017月: 安徽省合肥市金菱里克公司(工艺员)

  • 20019200612中国科学技术大学化学系有机化学专业(硕、博)


工作经历:

  • 2006.12-至今:常州大学石油化工学院

  • 2011.32011.8,加拿大国家研究所生化所(NRC-IBS),访问学者,从事神经氨酶抑制剂的合成。


研究方向:

  • 主要从事富勒烯化学的研究,围绕“新方法、新结构、新反应”开展一些对富勒烯进行化学修饰,目前集中于研究Cu (n)试剂和I (n)试剂促进的富勒烯环加成反应化学反应。

教学科研项目:

  • 2014.12-2016.12,碘试剂作用下富勒烯衍生化新方法研究,江苏省自然科学基金面上项目,项目编号BK20141171,主持人;

  • 2009.12-2012.12,富勒烯参与的自由基新反应研究,国家自然科学基金(青年)项目批准号20902039,主持人。

  • 2012.12-2015.12,基于[4+1][2+2][3+2]反应构建杂环的新方法研究,国家自然科学基金,项目批准号212020111,排名第二;

  • 2009.12-2012.12,江苏省自然科学金,新型14-二氢吡啶钙离子通道阻滞剂的设计合成和筛选,项目批准号 BK2009543,排名第二。


发表论文

  •  “Cu(OAc)2-Mediated Reaction of C60 with Ureas for the Preparation of Fulleroimidazolidinones”, Hai-Tao Yang,* Yi-Chen Tan, Yang Yang, Xiao-Qiang Sun, Chun-Bao Miao,J. Org. Chem.2016, 81, 1157-1163.

  •   “Cu(OAc)2-promoted reaction of [60]fullerene with primary amines or diamines”Xin-Wei Lu, Meng-Lei Xing, Chun-Bao Miao, Jia-Xing Li, Xiao-Qiang Sun* and Hai-Tao Yang*Org. Biomol. Chem., 2015, 13, 8405–8410.

  •   “Lewis Base-Catalyzed Reaction of Aziridinofullerene with Ureas for the Preparation of Fulleroimidazolidinones”, Meng-Lei Xing, Xin-Wei Lu, Chun-Bao Miao, Jia-Xing Li, Xiao-Qiang Sun, Hai-Tao Yang,*J. Org. Chem.2014, 79, 11774-11779. (二区TOPIF = 4.638)

  •  “BF3·Et2O- or DMAP-Catalyzed Double Nucleophilic Substitution Reaction of Aziridinofullerenes with Sulfamides or Amidines”, Hai-Tao Yang,* Meng-Lei Xing, Xin-Wei Lu, Jia-Xing Li, Jiang Cheng, Xiao-Qiang Sun, Chun-Bao Miao,J. Org. Chem.2014, 79, 11744-11749. (二区TOPIF = 4.638)

  •  “BF3Et2O-Catalyzed Formal [3+2] Reaction of Aziridinofullerenes with Carbonyl Compounds”, Hai-Tao Yang,* Meng-Lei Xing, Ye-Fei Zhu, Xiao-Qiang Sun, Jiang Cheng, Chun-Bao Miao, Fa-Bao Li,*J. Org. Chem.2014, 79, 1487-1492. (二区TOPIF = 4.638)

  •  “Hypervalent Iodine Reagent Mediated Diamination of [60]Fullerene with Sulfamides or Phosphoryl Diamides”, Hai-Tao Yang,* Xin-Wei Lu, Meng-Lei Xing, Xiao-Qiang Sun, Chun-Bao Miao,*Org. Lett. 2014, 16, 5882-5885. (二区TOPIF = 6.324)

  •   “Hypervalent Iodine Reagent-Mediated Reaction of [60]Fullerene with Amines”, Chun-Bao Miao,* Xin-Wei Lu, Ping Wu, Jiaxing Li, Wen-Long Ren, Meng-Lei xing, Xiao-Qiang Sun, Hai-Tao Yang,*J. Org. Chem.2013, 78, 12257-12262.

  •  “CuCl2-Mediated the Reaction of [60]Fullerene with Amines in the Presence or Absence of Dimethyl Acetylenedicarboxylate: Preparation of Fulleropyrroline or Aziridinofullerene Derivatives”, Hai-Tao Yang,* Xi-Chen Liang, Yan-Hong Wang, Yang Yang, Xiao-Qiang Sun,* Chun-Bao Miao,J. Org. Chem.2013, 78, 11992-11998.

  •  “PhI(OAc)2/I2-mediated [3+2] reaction of [60]fullerene with amides for the preparation of fullerooxazoles”, Hai-Tao Yang,* Wen-Long Ren, Chun-Ping Dong, Yang Yang, Xiao-Qiang Sun, Chun-Bao Miao,*Tetrahedron Lett.2013, 54, 6799-6803.

  •  “CuI-Catalyzed Oxidative [3+2] Reaction of Fullerene with Amidines or Amides Using Air as the Oxidant: Preparation of Fulleroimidazole or Fullerooxazole Derivatives”, Hai-Tao Yang,* Xi-Chen Liang, Yan-Hong Wang, Yang Yang, Xiao-Qiang Sun,* Chun-Bao Miao,Org. Lett.2013, 15, 4650-4653.

  •  “DMAP-Catalyzed [3+2] and [4+2] Cycloaddition Reactions between [60]fullerene and Unmodified Morita–Baylis–Hillman Adducts in the Presence of Ac2O”, Hai-Tao Yang,* Wen-Long Ren, Chun-Bao Miao, Chun-Ping Dong, Yang Yang, Hai-Tao Xi, Qi Meng, Yan Jiang, Xiao-Qiang Sun,*J. Org. Chem.2013, 78, 1163-1170.

  •  “Reaction of [60]fullerene with α-alkoxyl/acyloxyl/phenolyl ketoxime: unusual C-C and C-O bond cleavage” Hai-Tao Yang,* Wen-Long Ren, Xiao-Jiao Ruan, Zong-Yong Tian, Xi-Chen Liang, Chen Han, Xiao-Qiang Sun,* Chun-Bao Miao,Tetrahedron Lett.2013, 54, 1428-1431.

  •  “CuBr/PMDETA-Mediated Reactions of [60]Fullerene with Active Halides: Preparation of Methano[60]fullerene Derivatives”, Hai-Tao Yang,* Zong-Yong Tian, Xiao-Jiao Ruan, Min Zhang, Chun-Bao Miao, Xiao-Qiang Sun,*Eur. J. Org. Chem.2012, 4918-4922.



授权专利

  • 20121205,一种催化合成苄叉氰乙酸酯环氧化物的方法,ZL200910028420.X

  •  20140919,卡巴他赛的合成方法,zl201110162562.2




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