曹剑瑜

教授曹剑瑜
Email:  jycao@cczu.edu.cn; jyucao@hotmail.com

教育经历:

2006/09 – 2009/07, 中科院上海微系统与信息技术研究所, 材料物理与化学, 博士

2001/09 – 2004/07, 南京师范大学化学与环境科学学院, 物理化学, 硕士

工作经历：

2009/07 – 至今, 常州大学石油化工学院, 讲师(2006) 副教授(2011) 教授(2017) 博士生导师(2018)

2019/01 – 2019/12, 澳大利亚昆士兰大学生物工程与纳米技术研究所, 访问学者

2013/08 – 2014/08, 美国特拉华(Delaware)大学化学工程与分子工程系, 访问学者

荣誉与获奖：

江苏省高校“青蓝工程”中青年学术带头人(2019)

常州市自然科学论文三等奖(2019)

国家公派出国留学基金(2018)

常州市自然科学论文三等奖(2015)

江苏省高校“青蓝工程”中青年骨干教师(2014)

江苏省教育厅公派留学基金(2013)

常州市自然科学论文二等奖(2011)

江苏省企业博士人才项目(2011)

中国石油和化学工业协会(CPCIA)科技进步奖三等奖(2010)

常州市“831高层次创新创业人才培养工程”首批中青年骨干人才(2009)

中国科学院所长奖(2009)

社会兼职（社会兼职填是否担任过专业杂志编委、专业委员会委员、专业协会会员等）

中国化学会会员、国家基金委函评专家。

研究方向:

有机液流电池、新型二次电池、纳米电催化

科研项目:

[1]国家自然科学基金面上项目(21975033): 基于氧化还原活性共价有机框架聚合物的水系全有机二次电池设计(2020-2023), 66万, 主持, 在研.

[2]国家自然科学基金面上项目(21573025): 基于醌类衍生物电化学的全有机水系液流电池高电位电解质研究(2016-2019), 66万, 主持, 结题.

[3]国家自然科学基金青年基金项目(21103014):直接甲醇燃料电池石墨烯基扩散层电极及传质机理研究(2012-2014), 主持, 结题.

[4]江苏省自然科学基金项目(BK2012591):石墨烯负载金属氢氧化物/石墨烯不对称电化学电容器研究(2013-2014), 主持, 结题.

[5]江苏省企业博士集聚计划项目(2011Z0062)：直接甲醇燃料电池膜电极的有序结构设计与性能研究(2011-2013), 主持, 结题.

[6]江苏省太阳能电池材料与技术重点实验室开放课题(201106): 有序碳基复合储能材料的制备及其电极动力学机理研究(2012-2013), 主持, 结题.

研究论文(2017-2023)

1. Yanjun Shi*, Pengcheng Wang, Haiguang Gao, Wei Jin, Yanli Chen, Yucheng Huang, Tai-Rui Wu, De-Yin Wu, Juan Xu, Jianyu Cao(曹剑瑜)*, π-Conjugated N-heterocyclic compound with redox-active quinone and pyrazine moieties as a high-capacity organic cathode for aqueous zinc-ion batteries, Chem. Eng. J., 2023, 461, 141850.

2. Xue Xia,‡ Mengna Qin,‡ Yang Sun, Yanjun Shi, Juan Xu,* Yong-Miao Shen,* Dengfeng Guo, Zhidong Chen, Jianyu Cao(曹剑瑜)*, A high-capacity 1,2:3,4-dibenzophenazine anode integrated into carbon felt for an aqueous organic flow battery in alkaline media, Green Chem., 2022, 24, 8783-8790.

3. Caixing Wang,‡ Yanrong Wang,‡ Meng Tao,‡ Bo Yu, Kaiqiang Zhang, Jie Wei, Yuzhu Liu, Pengbo Zhang, Guochun Ding, Zuoxiu Tie*, Jianyu Cao(曹剑瑜)*, Zhong Jin*, Highly water-soluble 6-quinoxalinecarboxylic acid for high-voltage aqueous organic redox flow batteries, ACS Appl. Energy Mater., 2022, 5, 10379-10384.

4. Chuan-Wei Feng, Dan-Yan Wang, Hui-Ling Lu, Zi-Wei Xi, Yong-Miao Shen*, Jianyu Cao(曹剑瑜)*, Photocatalytic synthesis of sulfinamides and sulfoxides from nitroarenes and thiophenols, Org. Lett., 2022, 24, 4485-4489.

5. Wenfei Zhang, Yanli Chen*, Tai-Rui Wu, Xue Xia, Juan Xu, Zhidong Chen, Jianyu Cao(曹剑瑜)*, De-Yin Wu, Computational design of phenazine derivative molecules as redox-active electrolyte materials in alkaline aqueous organic flow batteries, New J. Chem., 2022, 46, 11662-11668.

6. Hongchao Zhang,‡ Qinghong Huang,‡ Xue Xia, Yanjun Shi, Yong-Miao Shen, Juan Xu,* Zhidong Chen and Jianyu Cao(曹剑瑜)*, Aqueous organic redox-targeting flow battery based on Nernstian-potential-driven anodic redoxtargeting reactions, J. Mater. Chem. A, 2022, 10, 6740-6747.

7. Zirui Liu,‡ Zheng Wang,‡ Yanjun Shi, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu* and Jianyu Cao(曹剑瑜)*, A high-capacity hexaazatrinaphthylene anode for aqueous organic hybrid flow batteries, J. Mater. Chem. A, 2021, 9, 27028-27033.

8. Jun Qiao, Zirui Liu, Zheng Wang, Meng Qin, Yanjun Shi, Juan Xu,* Zhidong Chen, and Jianyu Cao(曹剑瑜)*, Long-life aqueous H⁺/K⁺ dual-cation batteries based on dipyridophenazine//hexacyanoferrate electrodes, ACS Appl. Energy Mater. 2021, 4, 4903-4909.

9. Jun Qiao, Meng Qin, Yong-Miao Shen, Jianyu Cao(曹剑瑜),* Zhidong Chen and Juan Xu*, A rechargeable aqueous proton battery based on a dipyridophenazine anode and an indium hexacyanoferrate cathode, Chem. Commun., 2021, 57, 4307-4310.

10. Jianyu Cao(曹剑瑜), Junya Tian, Juan Xu* and Yonggang Wang*, Organic flow batteries: recent progress and perspectives, Energy & Fuels 2020, 34, 11, 13384-13411.

11. Wenbo Zhou, Wenjie Liu, Meng Qin, Zhidong Chen, Juan Xu*, Jianyu Cao(曹剑瑜)* and Jun Li*, Fundamental properties of TEMPO-based catholytes for aqueous redox flow batteries: effects of substituent groups and electrolytes on electrochemical properties, solubilities and battery performance, RSC Adv., 2020, 10, 21839-21844.

12. Yang Zhang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Juan Xu* and Chengzhong Yu, An organic-based aqueous hybrid flow battery with high power and long cycle life: tetrapyridophenazine/ferrocyanide system, J. Mater. Chem. A, 2020, 8, 6874-6881.

13.Binbin Wang, Yang Zhang, Ye Zhu, Yong-Miao Shen, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹剑瑜)*, Juan Xu*, Redox-active poly (6-(1H-pyrrol-1-yl) quinoxaline) as a novel organic anode material for aqueous hybrid flow batteries, J. Power Sources, 2020, 451, 227788.

14.Yang Zhang, Wenjie Liu, Zheng Wang, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu*, Jianyu Cao(曹剑瑜)*, Tetrapyridophenazine/graphene composites for aqueous hybrid flow battery anodes with long cycle life, Carbon, 2020, 161, 309-315.

15. Xiaolin Li, Yongsheng Zhou, Yingying Du, Juan Xu*, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹剑瑜)*, PtCu nanoframes as ultra-high performance electrocatalysts for methanol oxidation, Int. J. Hydrogen Energy, 2019, 44, 18050-18057.

16. Jianyu Cao(曹剑瑜), Fanfan Ding, Hongping Chen, Hongning Wang, Wenchang Wang, Zhidong Chen*, Juan Xu*, A new redox-active conjugated polymer containing anthraquinone pendants as anode material for aqueous all-organic hybrid-flow battery, J. Power Sources, 2019, 423, 316-322.

17. Juan Xu, Huada Cao, Chaoying Ni, Yan Wang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Design and synthesis of sandwich-like CoNi₂S₄@C@NiCo-LDH microspheres for supercapacitors, J. Solid State Electrochem., 2019, 23, 1513-1522.

18.Juan Xu, Yonghong Yang, Yan Wang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Enhanced electrochemical properties of manganese-based metal organic framework materials for supercapacitors, J. Appl. Electrochem., 2019, 1-12.

19. Mingming Dong, Hongping Chen, Juan Xu*, Zhidong Chen* and Jianyu Cao(曹剑瑜)*, Synthesis of Cu-decorated PtTe nanotubes with high electrocatalytic activity for oxygen reduction, J. Alloy. Compd., 2019, 770, 76-81.

20. Jianyu Cao(曹剑瑜), Meng Tao, Hongping Chen, Juan Xu*, Zhidong Chen*, A highly reversible anthraquinone-based anolyte for alkaline aqueous redox flow batteries, J. Power Sources, 2018, 386, 40-46.

21. Jianyu Cao(曹剑瑜), Yingying Du, Mingming Dong, Zhidong Chen*, Juan Xu*, Template-free synthesis of chain-like PtCu nanowires and their superior performance for oxygen reduction and methanol oxidation reaction, J. Alloy. Compd., 2018, 747, 124-130.

22. Jianyu Cao(曹剑瑜), Xiaodi Jia, Mengwei Guo, Yingying Du, Juan Xu* and Zhidong Chen*, Fe–N co-decorated hierarchically porous graphene as a highly efficient electrocatalyst for the oxygen reduction reaction, Sustain. Energ. Fuels, 2017, 2, 169-174.

23. Jianyu Cao(曹剑瑜), Zhentao Zhu, Juan Xu*, Meng Tao and Zhidong Chen*, Nitrogen-doped porous graphene as a highly efficient cathodic electrocatalyst for aqueous organic redox flow battery application, J. Mater. Chem. A, 2017, 5, 7944–7951.

24. Jianyu Cao(曹剑瑜), Yue Hu, Lijuan Chen, Juan Xu*, Zhidong Chen*, Nitrogen-doped carbon quantum dot/graphene hybrid nanocomposite as an efficient catalyst support for the oxygen reduction reaction, Int. J. Hydrogen Energy, 2017, 42, 2931-2942.

25. Juan Xu, Chaojie Ma, Jianyu Cao(曹剑瑜)* and Zhidong Chen*, Facile synthesis of core–shell nanostructured hollow carbon nanospheres@nickel cobalt double hydroxides as high-performance electrode materials for supercapacitors, Dalton Transactions, 2017, 46, 3276–3283.

26. Juan Xu, Kexing Hou, Zhengwei Ju, Chaojie Ma, Wenchang Wang, Cheng Wang, Jianyu Cao(曹剑瑜)* and Zhidong Chen*, Synthesis and Electrochemical Properties of Carbon Dots/Manganese Dioxide (CQDs/MnO₂) Nanoflowers for Supercapacitor Applications, J. Electrochem. Soc., 2017, 164(2), A430-A437.

授权专利

[1]一种锂离子电池负极材料及其制备方法(授权), 中国发明专利,CN201310147107.4(2014)

[2]一种磷酸铁锂-碳-二氧化硅复合材料及其制备方法(授权), 中国发明专利,201210382917.3(2014)

[3]一种碳载Co核-Pt壳纳米粒子催化剂及其制备方法(授权),中国发明专利,CN 201310524211.0(2015)(已转让)

[4]基于吡嗪多羧酸配体构筑金属锰有机框架化合物的方法及应用(授权), 中国发明专利,201811090629.4(2021)

[5]混合液流电池阴极用TEMPO基聚吡咯及制备方法(授权), 中国发明专利, 202010064852.2 (2021) (已转让)

[6]单晶硅太阳能电池表面处理用制绒剂及使用方法(授权), 中国发明专利,201110177294.1 (2014)

[7]高导电性柔性石墨烯膜电极的制备方法(授权), 中国发明专利,201310243138.X (2015)

[8]一种超级电容器用镍钴双氢氧化物/含氮碳纳米角复合材料及其制备方法(授权), 中国发明专利,201610414633.6(2018)

[9]一种有机电解液体系不对称电化学电容器及其制备方法(授权), 中国发明专利,201310350232.5(2015) (转让)

[10]一种含氮碳量子点/石墨相氮化碳复合光催化剂的制备方法(授权), 中国发明专利,201710497252.3(2019)

[11]一种基于金属有机配合物液流正极的水系单液流电池及其制备方法(授权), 中国发明专利,201710578191.3(2019)

[12]一种以碳纳米角/聚酰亚胺复合物为固体负极的邻菲罗啉铁配合物-水系半液流电池(授权), 中国发明专利,201811157300.5 (2021)(独占许可)

[13]基于含氧化还原活性侧基单元的共轭微孔聚合物负极的水系全有机混合液流电池(授权), 中国发明专利,202011355637.4 (2021)(独占许可)

[14]基于电活性吩嗪衍生物负极的碱性水系混合液流电池(授权), 中国发明专利,202011380434.0 (2021)(独占许可)

[15]一种COF负载的金属氢氧化物电极的制备方法及其应用(授权), 中国发明专利,201910619326.5 (2021)

[16]一种基于吡啶基吩嗪的高功率长寿命的中性水系混合液流电池(授权), 中国发明专利, 201911195708.6 (2022)(独占许可)

[17]一种基于聚吡咯喹喔啉负极的全水系混合液流电池及制备方法(授权), 中国发明专利, 201911073961.4 (2022)(独占许可)

[18]基于具有多种氧化态嗪类化合物的水系全有机二次电池(授权), 中国发明专利, 202110589675.4 (2022)