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曹剑瑜

   发布时间: 2014-07-15    访问次数: 9384

教授曹剑瑜
Email:  jycao@cczu.edu.cn; jyucao@hotmail.com

 

教育经历:

2006/09 – 2009/07, 中科院上海微系统与信息技术研究所, 材料物理与化学, 博士

2001/09 – 2004/07, 南京师范大学化学与环境科学学院, 物理化学, 硕士

 

工作经历:

2009/07 – 至今, 常州大学石油化工学院, 讲师(2006) 副教授(2011) 教授(2017) 博士生导师(2018)

2019/01 – 2019/12, 澳大利亚昆士兰大学生物工程与纳米技术研究所, 访问学者

2013/08 – 2014/08, 美国特拉华(Delaware)大学化学工程与分子工程系, 访问学者

 

荣誉与获奖

江苏省高校青蓝工程中青年学术带头人(2019)

常州市自然科学论文三等奖(2019)

国家公派出国留学基金(2018)

常州市自然科学论文三等奖(2015)

江苏省高校青蓝工程中青年骨干教师(2014)

江苏省教育厅公派留学基金(2013)

常州市自然科学论文二等奖(2011)

江苏省企业博士人才项目(2011)

中国石油和化学工业协会(CPCIA)科技进步奖三等奖(2010)

常州市“831高层次创新创业人才培养工程首批中青年骨干人才(2009)

中国科学院所长奖(2009)

 

社会兼职(社会兼职填是否担任过专业杂志编委、专业委员会委员、专业协会会员等)

中国化学会会员、国家基金委函评专家。

 

研究方向:

有机液流电池、新型二次电池、纳米电催化

 

科研项目:

[1]国家自然科学基金面上项目(21975033): 基于氧化还原活性共价有机框架聚合物的水系全有机二次电池设计(2020-2023), 66, 主持, 在研.

[2]国家自然科学基金面上项目(21573025): 基于醌类衍生物电化学的全有机水系液流电池高电位电解质研究(2016-2019), 66, 主持, 结题.

[3]国家自然科学基金青年基金项目(21103014): 直接甲醇燃料电池石墨烯基扩散层电极及传质机理研究(2012-2014), 主持, 结题.

[4]江苏省自然科学基金项目(BK2012591): 石墨烯负载金属氢氧化物/石墨烯不对称电化学电容器研究(2013-2014), 主持, 结题.

[5]江苏省企业博士集聚计划项目(2011Z0062)直接甲醇燃料电池膜电极的有序结构设计与性能研究(2011-2013), 主持, 结题.

[6]江苏省太阳能电池材料与技术重点实验室开放课题(201106): 有序碳基复合储能材料的制备及其电极动力学机理研究(2012-2013), 主持, 结题.

 

研究论文(2014-2022)

1. Hongchao Zhang,‡ Qinghong Huang,‡ Xue Xia, Yanjun Shi, Yong-Miao Shen, Juan Xu,* Zhidong Chen and Jianyu Cao(曹剑瑜)*, Aqueous organic redox-targeting flow battery based on Nernstian-potential-driven anodic redoxtargeting reactions, Journal of Materials Chemistry A, 2022, DOI: 10.1039/d1ta10763a.

2. Zirui Liu,‡ Zheng Wang,‡ Yanjun Shi, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu* and Jianyu Cao(曹剑瑜)*, A high-capacity hexaazatrinaphthylene anode for aqueous organic hybrid flow batteries, Journal of Materials Chemistry A, 2021, 9, 27028-27033.

3. Jun Qiao, Zirui Liu, Zheng Wang, Meng Qin, Yanjun Shi, Juan Xu,* Zhidong Chen, and Jianyu Cao(曹剑瑜)*, Long-life aqueous H+/K+ dual-cation batteries based on dipyridophenazine//hexacyanoferrate electrodes, ACS Appl. Energy Mater. 2021, 4, 4903-4909. 4. Jun Qiao, Meng Qin, Yong-Miao Shen, Jianyu Cao(曹剑瑜),* Zhidong Chen and Juan Xu*, A rechargeable aqueous proton battery based on a dipyridophenazine anode and an indium hexacyanoferrate cathode, Chem. Commun., 2021, 57, 4307-4310.

5. Jianyu Cao(曹剑瑜), Junya Tian, Juan Xu* and Yonggang Wang*, Organic flow batteries: recent progress and perspectives, Energy & Fuels 2020, 34, 11, 13384-13411.

6. Wenbo Zhou, Wenjie Liu, Meng Qin, Zhidong Chen, Juan Xu*, Jianyu Cao(曹剑瑜)* and Jun Li*, Fundamental properties of TEMPO-based catholytes for aqueous redox flow batteries: effects of substituent groups and electrolytes on electrochemical properties, solubilities and battery performance, RSC Advances, 2020, 10, 21839-21844.

7. Yang Zhang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Juan Xu* and Chengzhong Yu, An organic-based aqueous hybrid flow battery with high power and long cycle life: tetrapyridophenazine/ferrocyanide system, Journal of Materials Chemistry A, 2020, 8, 6874-6881.

8. Binbin Wang, Yang Zhang, Ye Zhu, Yong-Miao Shen, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹剑瑜)*, Juan Xu*, Redox-active poly(6-(1H-pyrrol-1-yl)quinoxaline) as a novel organic anode material for aqueous hybrid flow batteries, Journal of Power Sources, 2020, 451, 227788. https://doi.org/10.1016/j.jpowsour.2020.227788.

9. Yang Zhang, Wenjie Liu, Zheng Wang, Yong-Miao Shen, Wenchang Wang, Zhidong Chen, Juan Xu*, Jianyu Cao(曹剑瑜)*, Tetrapyridophenazine/graphene composites for aqueous hybrid flow battery anodes with long cycle life, Carbon, 2020, 161, 309-315. https://doi.org/10.1016/j.carbon.2020.01.092.

10. Xiaolin Li, Yongsheng Zhou, Yingying Du, Juan Xu*, Wenchang Wang, Zhidong Chen*, Jianyu Cao(曹剑瑜)*, PtCu nanoframes as ultra-high performance electrocatalysts for methanol oxidation, International Journal of Hydrogen Energy, 2019, 44, 18050-18057. https://doi.org/10.1016/j.ijhydene.2019.05.072.

11. Jianyu Cao(曹剑瑜), Fanfan Ding, Hongping Chen, Hongning Wang, Wenchang Wang, Zhidong Chen*, Juan Xu*, A new redox-active conjugated polymer containing anthraquinone pendants as anode material for aqueous all-organic hybrid-flow battery, Journal of Power Sources, 2019, 423, 316-322. https://doi.org/10.1016/j.jpowsour.2019.03.098.

12. Juan Xu, Huada Cao, Chaoying Ni, Yan Wang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Design and synthesis of sandwich-like CoNi2S4@C@NiCo-LDH microspheres for supercapacitors, Journal of Solid State Electrochemistry, 2019, 23, 1513-1522. https://doi.org/10.1007/s10008-019-04246-0.

13. Juan Xu, Yonghong Yang, Yan Wang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Enhanced electrochemical properties of manganese-based metal organic framework materials for supercapacitors, Journal of Applied Electrochemistry, 2019, 1-12. https://doi.org/10.1007/s10800-019-01352-9.

14. Mingming Dong, Hongping Chen, Juan Xu*, Zhidong Chen* and Jianyu Cao(曹剑瑜)*, Synthesis of Cu-decorated PtTe nanotubes with high electrocatalytic activity for oxygen reduction, Journal of Alloys and Compounds, 2019, 770, 76-81. https://doi.org/10.1016/j.jallcom.2018.08.052

15. Jianyu Cao(曹剑瑜), Meng Tao, Hongping Chen, Juan Xu*, Zhidong Chen*, A highly reversible anthraquinone-based anolyte for alkaline aqueous redox flow batteries, Journal of Power Sources, 2018, 386, 40-46. https://doi.org/10.1016/j.jpowsour.2018.03.041

16. Jianyu Cao(曹剑瑜), Yingying Du, Mingming Dong, Zhidong Chen*, Juan Xu*, Template-free synthesis of chain-like PtCu nanowires and their superior performance for oxygen reduction and methanol oxidation reaction, Journal of Alloys and Compounds, 2018, 747, 124-130. https://doi.org/10.1016/j.jallcom.2018.03.025

17. Jianyu Cao(曹剑瑜), Xiaodi Jia, Mengwei Guo, Yingying Du, Juan Xu* and Zhidong Chen*, Fe–N co-decorated hierarchically porous graphene as a highly efficient electrocatalyst for the oxygen reduction reaction, Sustainable Energy & Fuels, 2, 169-174, DOI: 10.1039/c7se00458c (2018).

18. Jianyu Cao(曹剑瑜), Zhentao Zhu, Juan Xu*, Meng Tao and Zhidong Chen*, Nitrogen-doped porous graphene as a highly efficient cathodic electrocatalyst for aqueous organic redox flow battery application, Journal of Materials Chemistry A, 2017, 5, 7944–7951, DOI: 10.1039/c7ta00873b.

19. Jianyu Cao(曹剑瑜), Yue Hu, Lijuan Chen, Juan Xu*, Zhidong Chen*, Nitrogen-doped carbon quantum dot/graphene hybrid nanocomposite as an efficient catalyst support for the oxygen reduction reaction, International Journal of Hydrogen Energy, 2017, 42, 2931-2942, http://dx.doi.org/10.1016/j.ijhydene.2017.01.029.

20. Juan Xu, Chaojie Ma, Jianyu Cao(曹剑瑜)* and Zhidong Chen*, Facile synthesis of core–shell nanostructured hollow carbon nanospheres@nickel cobalt double hydroxides as high-performance electrode materials for supercapacitors, Dalton Transactions, 2017, 46, 3276–3283, DOI: 10.1039/c6dt04759a.

21. Juan Xu, Kexing Hou, Zhengwei Ju, Chaojie Ma, Wenchang Wang, Cheng Wang, Jianyu Cao(曹剑瑜)* and Zhidong Chen*, Synthesis and Electrochemical Properties of Carbon Dots/Manganese Dioxide (CQDs/MnO2) Nanoflowers for Supercapacitor Applications, Journal of The Electrochemical Society, 2017, 164(2), A430-A437, DOI: 10.1149/2.1241702jes.

22. Jianyu Cao(曹剑瑜), Zhentao Zhu, Weifang Zhao, Juan Xu* and Zhidong Chen*, Facile Synthesis of Carbon-Supported Ultrasmall Ag@Pd Core-Shell Nanocrystals with Superior Electrocatalytic Activity for Direct Formic Acid Fuel Cell Application, Chinese Journal of Chemistry, 2016, 34, 1086-1092, DOI: 10.1002/cjoc.201600366.

23. J. Xu, Y. Xue, J. Cao(曹剑瑜),* G. Wang, Y. Li, W. Wang and Z. Chen*, Carbon quantum dots/nickel oxide (CQDs/NiO) nanorods with high capacitance for supercapacitors, RSC Advances, 2016, 6, 5541–5546, DOI: 10.1039/c5ra24192h.

24. Juan Xu, Chao Yang, Yufei Xue, Cheng Wang, Jianyu Cao(曹剑瑜)*, Zhidong Chen*, Facile synthesis of novel metal-organic nickel hydroxide nanorods for high performance supercapacitor, Electrochimica Acta 2016, 211, 595–602, http://dx.doi.org/10.1016/j.electacta.2016.06.090.

25. Juan Xu, Zhengwei Ju, Jianyu Cao(曹剑瑜)*, Wenchang Wang, Cheng Wang, Zhidong Chen*, Microwave synthesis of nitrogen-doped mesoporous carbon/nickelcobalt hydroxide microspheres for high-performance supercapacitors, Journal of Alloys and Compounds, 2016, 689, 489-499, http://dx.doi.org/10.1016/j.jallcom.2016.08.006.

26. Juan Xu, Guoxin Wang, Jianyu Cao(曹剑瑜)*, Yufei Xue, Yang Li, Wenchang Wang, Zhidong Chen*, Supercapacitor performances of rich nitrogen-doped mesoporous graphene fabricated by a facile template-free copyrolysis process, Ionics, 2016, 22, 1177–1184, DOI 10.1007/s11581-015-1624-7.

27. Jianyu Cao(曹剑瑜), Mengwei Guo, Jinyan Wu, Juan Xu, Wenchang Wang, Zhidong Chen*, Carbon-supported Ag@Pt core-shell nanoparticles with enhanced electrochemical activity for methanol oxidation and oxygen reduction reaction, Journal of Power Sources, 2015, 277, 155-160, http://dx.doi.org/10.1016/j.jpowsour.2014.12.017.

28. Jianyu Cao(曹剑瑜), Xiaojuan Yin, Liangduo Wang, Mengwei Guo, Juan Xu, Zhidong Chen*, Enhanced electrocatalytic activity of platinum nanoparticles supported on nitrogen-modified mesoporous carbons for methanol electrooxidation, International Journal of Hydrogen Energy, 2015, 40, 2971-2978, http://dx.doi.org/10.1016/j.ijhydene.2015.01.014.

29. Juan Xu, Xicheng Wei, Jianyu Cao(曹剑瑜)*, Yuanzhu Dong, Guoxin Wang, Yufei Xue, Wenchang Wang, Zhidong Chen*, Facile synthesis and electrochemical performances of binder-free flexible graphene/acetylene black sandwich film, Electrochimica Acta, 2015, 152, 391–397, http://dx.doi.org/10.1016/j.electacta.2014.11.201.

30. Juan Xu, Yang Li, Jianyu Cao(曹剑瑜)*, Rongrong Meng, Wenchang Wang and Zhidong Chen*, Preparation of graphene-supported highly dispersed nickel nanoparticles for the improved generation of hydrogen from ball-milled LiBH4, Catalysis Science & Technology, 2015, 5, 1821–1828, DOI: 10.1039/c4cy01276c.

31. Jianyu Cao(曹剑瑜), Hui Zhuang, Mengwei Guo, Hongning Wang, Juan Xu* and Zhidong Chen*, Facile preparation of mesoporous graphenes by the sacrificial template approach for direct methanol fuel cell application, Journal of Materials Chemistry A, 2014, 2, 19914–19919, DOI: 10.1039/c4ta05100a.

32. Jianyu Cao(曹剑瑜)*, Liangduo Wang, Lingzheng Song, Juan Xu, Hongning Wang, Zhidong Chen, Qinghong Huang, Hui Yang*, Novel cathodal diffusion layer with mesoporous carbon for the passive direct methanol fuel cell, Electrochimica Acta, 2014, 118, 163–168, http://dx.doi.org/10.1016/j.electacta.2013.11.140.

授权专利

[1]曹剑瑜,吴金燕,许娟,郭梦薇,王文昌,陈智栋, 一种碳载Co-Pt壳纳米粒子催化剂及其制备方法(授权), 中国发明专利, CN 201310524211.0(2015)

[2]曹剑瑜,王进,许娟,展亮亮,陈智栋, 一种锂离子电池负极材料及其制备方法(授权), 中国发明专利, CN201310147107.4(2014)

[3]曹剑瑜,周慧,陈智栋,许娟,王文昌, 一种磷酸铁锂--二氧化硅复合材料及其制备方法(授权), 中国发明专利, 201210382917.3(2014)


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