童晓峰教授
E-mail: txf@cczu.edu.cn
教育经历：
1995年—1999年，北京师范大学，本科
1999年—2005年，中科院上海有机化学有机所，博士
工作经历：
2005年—2006年，德国Leibniz催化研究所，博士后
2006年—2015年，华东理工大学，副教授、教授，博士生导师
2016年至今，常州大学石油化工学院，教授
研究方向：
Lewis碱催化环加成反应
金属催化碳-卤键形成方法
杂环合成新方法创制
主持的科研项目主要包括：
1）“Pd(0)-催化的烷基卤代烃形成反应研究”，面上项目(21472042)，2015年至 2018年。
2）“加成-消除策略在亲核催化环加成反应中的应用”，面上项目 (21272066)， 2013年至 2016年。
3）“三苯基膦催化的贫电子端炔参与的环加成反应研究”，青年基金(21002025)，2011年至 2013年。
4）“叔膦催化环加成反应研究”，新世纪优秀人才支持计划(NCET-12-0851)，2012年至 2015年。
5）“叔膦催化的贫电子端炔与活化烯烃的环加成反应研究”，上海市科技启明星(11QA1401700), 2011年至2013年。
近5年发表论文：
(1) Li, Falin; Chen, Jiangfei; Hou, Yading; Tong, Xiaofeng*, 1,3-Dipolar Cycloadditions of 4-Acetoxy Allenoates: Access to 2,3-Dihydropyrazoles, 2,3-Dihydroisoxazoles, and Indolizines, Org. Lett. 2015, 17(21), 5376-5379.
(2) Liu, Qiang; Chen, Chen; Tong, Xiaofeng*, Pd(0)-Catalyzed Atom Transfer Radical Cyclization of N-allyl-alpha-chloroamides: Highly Stereoselective Synthesis of Substituted γ-Lactam, Tetrahedron Lett. 2015, 56(30), 4483-4485.
(3) Cheng, Mian; Liu, Jian-Kang; Tong, Xiaofeng*; Tian, Pin*, Amine-promoted Asymmetric [4+2] Cycloadditions of α-Acetoxymethyl Allenoate and Dual Activated Alkenes: Stereoselective Synthesis of Poly-substituted Cyclohexenes, Tetrahedron Lett. 2015, 56(25), 3864-3867.
(4) Gu, Yiting; Hu, Pengfei; Ni, Chunjie; Tong, Xiaofeng*, Phosphine-Catalyzed Addition/Cycloaddition Domino Reactions of '-Acetoxy Allenoate: Highly Stereoselective Access to 2-Oxabicyclo[3.3.1]nonane and Cyclopenta[a]pyrrolizine, J. Am. Chem. Soc. 2015, 137(19), 6400-6406.
(5) Gu, Yiting; Li, Falin; Hu, Pengfei; Tong, Xiaofeng*, Tertiary Amine-Catalyzed (4+2) Annulations of delta-Acetoxy Allenoates: Synthesis of Multisubstituted 4H-Pyran and 4H-Chromene, Org. Lett. 2015, 17(5), 1106-1109.
(6) Chen, Chen; Hou, Longlei; Cheng, Mian; Tong, Xiaofeng*, Palladium(0)-Catalyzed Iminohalogenation of Alkenes: Synthesis of 2-Halomethyl Dihydropyrroles and Mechanistic Insights into the Alkyl Halide Bond Formation, Angew. Chem. Int. Ed. 2015, 54(10), 3092-3096.
(7) Quan, Shasha; Wang, Yuanyuan; Zheng, Kewen*; Tong, Xiaofeng*, Rh(III)-Catalyzed Hydrative Cyclization of 1,6-allenynes: Synthesis of Six-membered Nitrogen and Oxygen Heterocycles, Tetrahedron Lett. 2015, 56(1), 215-217.
(8) Chen, Chen; Hu, Jian; Su, Jianhua; Tong, Xiaofeng*, Synthesis of Substituted γ-Lactam via Pd(0)-catalyzed Cyclization of Alkene-tethered Carbamoyl Chloride, Tetrahedron Lett. 2014, 55(21), 3229-3231.
(9) Xie, Zheng; Wu, Pan; Cai, Liangzhen; Tong, Xiaofeng*, Palladium-Catalyzed Cyclization of Vinyl iodide-tethered Allensulfonamide, Tetrahedron Lett. 2014, 55(13), 2160-2162.
(10) Dong, Wei; Hu, Pengfei; Hu, Jian; Tong, Xiaofeng*, Lewis Base-catalyzed Divergent Isomerizations of 5-Hydroxyl-2,3-dienoate, Tetrahedron Lett. 2014, 55(10), 1682-1685.
(11) Chen, Chen; Tong, Xiaofeng*, Synthesis of Organic Halides via Palladium(0) Catalysis Org, Chem. Front. 2014, 1(4), 439-446.
(12) Hu, Pengfei; Hu, Jian; Jiao, Haijun; Tong, Xiaofeng*, Amine-Promoted Asymmetric (4+2) Annulations for the Enantioselective Synthesis of Tetrahydropyridines: A Traceless and Recoverable Auxiliary Strategy, Angew. Chem. Int. Ed. 2013, 52(20), 5319-5322.
(13) Chen, Chen; Su, Jianhua; Tong, Xiaofeng*, Rhodium-Catalyzed Carbocyclization and Chlorosulfonylation of 1,6-Enynes with Sulfonyl Chlorides, Chem. Eur. J. 2013, 19(16), 5014-5018.
(14) Hu, Jian; Dong, Wei; Wu, Xin-Yan; Tong, Xiaofeng*, PPh3-Catalyzed (3+3) Annulations of 5-Acetoxypenta-2,3-dienoate with 1C,3O-Bisnucleophiles: Facile Entry to Stable Monocyclic 2H-Pyrans, Org. Lett. 2012, 14(21), 5530-5533.
(15) Hu, Jian; Dong, Wei; Wu, Xin-Yan; Tong, Xiaofeng*, Tertiary Amine-Triggered Cascade SN2/Cycloaddition: An Efficient Construction of Complex Azaheterocycles under Mild Conditions. Org. Lett. 2012, 14(19), 5074-5077.
(16) Wu, Pan; Liu, Hui; Tong, Xiaofeng*, Synthesis of 3-Pyrroline via Domino Heck-aza-Michael Reaction, Tetrahedron Lett. 2012, 53(35), 4673-4675.
(17) Li, Kun; Hu, Jian; Liu, Hui; Tong, Xiaofeng*, Amine-catalyzed Formal (3+3) Annulations of 2-(Acetoxymethyl)buta-2,3-dienoate with Sulfur Ylides: Synthesis of 4H-pyrans Bearing a Vinyl Sulfide Group, Chem. Commun. 2012, 48(23), 2900-2902.
(18) Liu, Hui; Wang, Limin; Tong, Xiaofeng*, Palladium-catalyzed Heck-type Reaction of Oxime Ether Bearing a Pendant Vinyl Iodide Moiety, Chem. Commun. 2011, 47(44), 12206-12208.
(19) Liu, Hui; Chen, Chen; Wang, Limin; Tong, Xiaofeng*, Pd(0)-Catalyzed Iodoalkynation of Norbornene Scaffolds: The Remarkable Solvent Effect on Reaction Pathway, Org. Lett. 2011, 13(19), 5072-5075.
(20) Wang, Xiaojun; Fang, Tong; Tong, Xiaofeng*, Enantioselective Amine-Catalyzed [4+2] Annulations of Allenoates and Oxo-dienes: An Asymmetric Synthesis of Dihydropyrans, Angew. Chem. Int. Ed. 2011, 50(23), 5361-5364.
(21) Liu, Hui; Li, Chaolong; Qiu, Dong*; Tong, Xiaofeng*, Palladium-Catalyzed Cycloisomerizations of (Z)-1-Iodo-1,6-dienes: Iodine Atom Transfer and Mechanistic Insight to Alkyl Iodide Reductive Elimination, J. Am. Chem. Soc. 2011, 133(16), 6187-6193.
