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童晓峰

   发布时间: 2016-09-13    访问次数: 4326

童晓峰教授

E-mail: txf@cczu.edu.cn


教育经历:

  • 1995年—1999年,北京师范大学,本科

  • 1999年—2005年,中科院上海有机化学有机所,博士

工作经历:

  • 2005年—2006年,德国Leibniz催化研究所,博士后

  • 2006年—2015年,华东理工大学,副教授、教授,博士生导师

  • 2016年至今,常州大学石油化工学院,教授


研究方向:

  • Lewis碱催化环加成反应

  • 金属催化碳-卤键形成方法

  • 杂环合成新方法创制


主持的科研项目主要包括:

1)“Pd(0)-催化的烷基卤代烃形成反应研究”,面上项目(21472042)2015年至 2018年。

2)“加成-消除策略在亲核催化环加成反应中的应用”,面上项目 (21272066)2013年至 2016年。

3三苯基膦催化的贫电子端炔参与的环加成反应研究”,青年基金(21002025)2011年至 2013年。

4叔膦催化环加成反应研究”,新世纪优秀人才支持计划(NCET-12-0851)2012年至 2015年。

5叔膦催化的贫电子端炔与活化烯烃的环加成反应研究”,上海市科技启明星(11QA1401700), 2011年至2013年。



5年发表论文:

(1) Li, Falin; Chen, Jiangfei; Hou, Yading; Tong, Xiaofeng*, 1,3-Dipolar Cycloadditions of 4-Acetoxy Allenoates: Access to 2,3-Dihydropyrazoles, 2,3-Dihydroisoxazoles, and Indolizines, Org. Lett. 2015, 17(21), 5376-5379.

(2) Liu, Qiang; Chen, Chen; Tong, Xiaofeng*, Pd(0)-Catalyzed Atom Transfer Radical Cyclization of N-allyl-alpha-chloroamides: Highly Stereoselective Synthesis of Substituted γ-Lactam, Tetrahedron Lett. 2015, 56(30), 4483-4485.

(3) Cheng, Mian; Liu, Jian-Kang; Tong, Xiaofeng*; Tian, Pin*, Amine-promoted Asymmetric [4+2] Cycloadditions of α-Acetoxymethyl Allenoate and Dual Activated Alkenes: Stereoselective Synthesis of Poly-substituted Cyclohexenes, Tetrahedron Lett. 2015, 56(25), 3864-3867.

(4) Gu, Yiting; Hu, Pengfei; Ni, Chunjie; Tong, Xiaofeng*, Phosphine-Catalyzed Addition/Cycloaddition Domino Reactions of '-Acetoxy Allenoate: Highly Stereoselective Access to 2-Oxabicyclo[3.3.1]nonane and Cyclopenta[a]pyrrolizine, J. Am. Chem. Soc. 2015, 137(19), 6400-6406.

(5) Gu, Yiting; Li, Falin; Hu, Pengfei; Tong, Xiaofeng*, Tertiary Amine-Catalyzed (4+2) Annulations of delta-Acetoxy Allenoates: Synthesis of Multisubstituted 4H-Pyran and 4H-Chromene, Org. Lett. 2015, 17(5), 1106-1109.

(6) Chen, Chen; Hou, Longlei; Cheng, Mian; Tong, Xiaofeng*, Palladium(0)-Catalyzed Iminohalogenation of Alkenes: Synthesis of 2-Halomethyl Dihydropyrroles and Mechanistic Insights into the Alkyl Halide Bond Formation, Angew. Chem. Int. Ed. 2015, 54(10), 3092-3096.

(7) Quan, Shasha; Wang, Yuanyuan; Zheng, Kewen*; Tong, Xiaofeng*, Rh(III)-Catalyzed Hydrative Cyclization of 1,6-allenynes: Synthesis of Six-membered Nitrogen and Oxygen Heterocycles, Tetrahedron Lett. 2015, 56(1), 215-217.

(8) Chen, Chen; Hu, Jian; Su, Jianhua; Tong, Xiaofeng*, Synthesis of Substituted γ-Lactam via Pd(0)-catalyzed Cyclization of Alkene-tethered Carbamoyl Chloride, Tetrahedron Lett. 2014, 55(21), 3229-3231.

(9) Xie, Zheng; Wu, Pan; Cai, Liangzhen; Tong, Xiaofeng*, Palladium-Catalyzed Cyclization of Vinyl iodide-tethered Allensulfonamide, Tetrahedron Lett. 2014, 55(13), 2160-2162.

(10) Dong, Wei; Hu, Pengfei; Hu, Jian; Tong, Xiaofeng*, Lewis Base-catalyzed Divergent Isomerizations of 5-Hydroxyl-2,3-dienoate, Tetrahedron Lett. 2014, 55(10), 1682-1685.

(11) Chen, Chen; Tong, Xiaofeng*, Synthesis of Organic Halides via Palladium(0) Catalysis Org, Chem. Front. 2014, 1(4), 439-446.

(12) Hu, Pengfei; Hu, Jian; Jiao, Haijun; Tong, Xiaofeng*, Amine-Promoted Asymmetric (4+2) Annulations for the Enantioselective Synthesis of Tetrahydropyridines: A Traceless and Recoverable Auxiliary Strategy, Angew. Chem. Int. Ed. 2013, 52(20), 5319-5322.

(13) Chen, Chen; Su, Jianhua; Tong, Xiaofeng*, Rhodium-Catalyzed Carbocyclization and Chlorosulfonylation of 1,6-Enynes with Sulfonyl Chlorides, Chem. Eur. J. 2013, 19(16), 5014-5018.

(14) Hu, Jian; Dong, Wei; Wu, Xin-Yan; Tong, Xiaofeng*, PPh3-Catalyzed (3+3) Annulations of 5-Acetoxypenta-2,3-dienoate with 1C,3O-Bisnucleophiles: Facile Entry to Stable Monocyclic 2H-Pyrans, Org. Lett. 2012, 14(21), 5530-5533.

(15) Hu, Jian; Dong, Wei; Wu, Xin-Yan; Tong, Xiaofeng*, Tertiary Amine-Triggered Cascade SN2/Cycloaddition: An Efficient Construction of Complex Azaheterocycles under Mild Conditions. Org. Lett. 2012, 14(19), 5074-5077.

(16) Wu, Pan; Liu, Hui; Tong, Xiaofeng*, Synthesis of 3-Pyrroline via Domino Heck-aza-Michael Reaction, Tetrahedron Lett. 2012, 53(35), 4673-4675.

(17) Li, Kun; Hu, Jian; Liu, Hui; Tong, Xiaofeng*, Amine-catalyzed Formal (3+3) Annulations of 2-(Acetoxymethyl)buta-2,3-dienoate with Sulfur Ylides: Synthesis of 4H-pyrans Bearing a Vinyl Sulfide Group, Chem. Commun. 2012, 48(23), 2900-2902.

(18) Liu, Hui; Wang, Limin; Tong, Xiaofeng*, Palladium-catalyzed Heck-type Reaction of Oxime Ether Bearing a Pendant Vinyl Iodide Moiety, Chem. Commun. 2011, 47(44), 12206-12208.

(19) Liu, Hui; Chen, Chen; Wang, Limin; Tong, Xiaofeng*, Pd(0)-Catalyzed Iodoalkynation of Norbornene Scaffolds: The Remarkable Solvent Effect on Reaction Pathway, Org. Lett. 2011, 13(19), 5072-5075.

(20) Wang, Xiaojun; Fang, Tong; Tong, Xiaofeng*, Enantioselective Amine-Catalyzed [4+2] Annulations of Allenoates and Oxo-dienes: An Asymmetric Synthesis of Dihydropyrans, Angew. Chem. Int. Ed. 2011, 50(23), 5361-5364.

(21) Liu, Hui; Li, Chaolong; Qiu, Dong*; Tong, Xiaofeng*, Palladium-Catalyzed Cycloisomerizations of (Z)-1-Iodo-1,6-dienes: Iodine Atom Transfer and Mechanistic Insight to Alkyl Iodide Reductive Elimination, J. Am. Chem. Soc. 2011, 133(16), 6187-6193.


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