姓 名

 李正义

 性别

 男

 出生年月

 1979.8

 职称

 副教授

 

单 位

 常州大学石油化工学院

 政治面貌

 中共党员

 所属学位点

 有机化学

研究方向

 有机合成

 超分子化学

 不对称合成及催化

学校及

社会兼职

 石油化工学院教学办公室主任

主要从事《有机化学》、《有机化学实验》课程的教学和本科生、硕士研究生毕业论文指导工作。

 

1、   基于杯芳烃平台的手性超分子催化剂的设计、合成及其催化的不对称反应研究，国家自然科学基金（21002009）

2、   可调控降解的轴手性高分子材料的研发，江苏省高校自然科学研究重大项目（12KJA150002）

3、   超分子催化手性医药中间体的合成，常州市科技项目（CJ20115019）

4、   手性杯[4]芳烃的合成及其在不对称催化和分子识别中的应用，常州大学项目（ZMF10020002）

 

1.        Zhengyi Li, Ling Ge, Liang Chen, Qiu-Zheng Tang, Lin-Lin Jin and Xiaoqiang Sun, Synthesis and Crystal Structure of 3,9-Bis(pyridin-2-yl)-2,4,8,10-tetraoxaspiro[5.5]undecane. Chinese J. Struct. Chem.2012, 31(5), 728-732.

2.        Zheng-Yi Li, Jia-Wen Chen, Ying Liu, Wei Xia, Leyong Wang, The Use of Calixarene in Asymmetric Catalysis. Curr. Org. Chem. 2011, 15, 39–61.

3.        Zheng-Yi Li, Huaijie Xing, Guoli Huang, Xiaoqiang Sun, Juli Jiang, Leyong Wang, Novel supramolecular organocatalysts of hydroxyprolinamide based on calix[4]arene scaffold for the enantioselective Biginelli reaction. Sci China Chem, 2011, 54(11), 1726-1734.

4.        Yang-Fan Guan, Zheng-Yi Li, Meng-Fei Ni, Chen Lin, Juli Jiang, Yi-Zhi Li, and Leyong Wang, Chiral Moieties-Oriented Single-Stranded Helical Assembly of Calix[4]azacrown Derivatives. Cryst. Growth Des., 2011, 11 (7), 2684–2689.

5.        Zhengyi Li, Beibei Zhou, Liang Chen, Ling Ge and Xiaoqiang Sun, rac-3,9-Bis(3-chlorophenyl)-2,4,8,10-tetraoxaspiro[5.5]undecane. Acta Cryst.2011, E67, o2672.

6.        Xin Chen, Zhengyi Li, Xiaoqiang Sun, Hongzhao Ma, Xiaoxin Chen, Jie Ren, Kun Hu, New method for synthesis of sulforaphane and the related isothiocyanates. Synthesis2011, 3991–3996.

7.        Zheng-Yi Li, Cheng-Xi Lu, Guoli Huang, Jie-Jie Ma, Hongsheng Sun, Leyong Wang, Yi Pan, Novel Prolinamide Organocatalysts Based on Calix[4]arene Scaffold for the Enantioselective Direct Aldol Reaction. Lett. Org. Chem.2010, 7, 461–466.

8.        Zhengyi Li, Liang Chen, Qiuzheng Tang and Xiaoqiang Sun, 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane. Acta Cryst.2010, E66, o3368.

9.        Xiaoqiang Sun, Liang Chen, Yan Jiang and Zhengyi Li*,3,3,9,9-Tetraphenyl-2,4,8,10-tetraoxaspiro[5.5]undecane. Acta Cryst.2010, E66, o3035. (4/4)

10.     Zhengyi Li, Qiuzheng Tang, Kang Wu, Shuling Yu and Xiaoqiang Sun, 3,9-Bis(2,4-dichlorophenyl)-2,4,8,10-tetraoxaspiro[5.5]undecane. Acta Cryst.2010, E66, o1864.

11.     Xiaoqiang Sun, Shu-Ling Yu, Zheng-Yi Li, Yang Yang, Crystal X-ray diffraction guided NMR analysis of 3,9-diaryl-2,4,8,10-tetraoxaspiro[5.5]undecanes under differently shielding effect of terminal aromatic rings. J. Mol. Struct.2010, 973, 152–156.

12.     Qi Meng, Juan-Juan Chen, Zheng-Yi Li, Dan-Feng Li, Gui-Yong Wu and Xiao-Qiang Sun, Synthesis and special structure of a novel low-generation amide dendrimer with pseudo-symmetric branch distribution. J. Chem. Res.2010, 432–434.

13.     Zheng-YiLi,Jia-Wen Chen, Leyong Wang, Yi Pan, Highly Enantioselective Direct Aldol Reaction Catalyzed by Proline Based on Calix[4]arene Scaffold in the Presence of Water. Synlett2009, 2356–2360.

14.     Zheng-YiLi, Ming-Yu Teng, Jie-Jie Ma, Ji Huang, Leyong Wang, Yi Pan, Unprecedented Synthesis of Chiral Calix[4](Aza)Crowns and Potent Encapsulating Methanol. Sci China Ser B-Chem2009, 52, 497–504.

15.     Zheng-YiLi, Jie-Jie Ma, Jia-Wen Chen, Yi Pan, Juli Jiang, Leyong Wang, High-performance Liquid Chromatography Study of the Nitration Course of Tetrabutoxycalix[4]arene at the Upper Rim: Determination of the Optimum Conditions for the Preparation of 5,11,17-Trinitro-25,26,27,28-tetrabutoxycalix[4]arene. Chin. J. Chem.2009, 27, 2031–2036.

16.     Zhengyi Li, Dinghao Yuan, Haitao Xi, Xiaoqiang Sun, 25,26,27,28-Tetrabutoxy- 5,11,17,23-tetra-tert-butylcalix[4]arene chloroform tetrasolvate dehydrate. Acta Cryst.2009, E65, o1697.

 

1、   李正义,马鸿钊，陈新，孙小强，何向前，一种制备异硫氰酸酯的方法，CN201110420441.3

2、   陈新，孙小强，李正义，任杰，胡昆，萝卜硫素的合成方法，CN201110162525.1

 

2011中国石油和化学工业联合会科技进步二等奖（2011JBR0476-2-6）.